Patented method for the preparation of copper-titanium dioxide core-shell nanoparticles

In recent years, core-shell structured nanoparticles composed of precious metals and titanium dioxide have attracted significant attention in the scientific community. These structures leverage the unique properties of noble metals as the core, which can modify the energy band structure of the surrounding titanium dioxide semiconductor. This modification enables the material to absorb visible light more effectively. Additionally, when noble metal particles come into contact with titanium dioxide, electrons migrate between the two surfaces, leading to a buildup of negative charge on the metal surface and an excess of positive holes in the semiconductor. This separation of charges prevents the recombination of photogenerated electron-hole pairs, thereby enhancing the efficiency of charge transfer and photocatalytic performance. Researchers at the Institute of Physical and Chemical Technology, Chinese Academy of Sciences, have developed a novel method for preparing copper-titanium dioxide core-shell nanoparticles. The process involves dissolving cuprous chloride in ammonia water, followed by the addition of polyethylene glycol aqueous solution, sodium citrate, ascorbic acid, tetrabutyl titanate (in absolute ethanol), and urea. The mixture is stirred at room temperature and then placed in a PTFE-lined stainless steel hydrothermal reactor. By carefully controlling the reaction temperature and time, near-spherical core-shell nanoparticles are successfully synthesized. In this method, ascorbic acid functions as a reducing agent, converting monovalent copper ions into metallic copper, while polyethylene glycol acts as a soft template that helps control the morphology and size distribution of the nanoparticles. The resulting copper-titanium dioxide core-shell nanoparticles exhibit uniform size and controllable particle dimensions. The outer layer consists of anatase-type titanium dioxide, while the inner core is made of metallic copper. These nanoparticles show great potential as electrode materials and photocatalysts in dye-sensitized solar cells. This innovative preparation method has been granted a national invention patent on May 2nd, with the patent number ZL 201110258150.9. The process is not only simple and environmentally friendly but also cost-effective, making it a promising approach for large-scale production and practical applications in renewable energy and environmental technologies.

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